This method is used for the collection and analysis of halgenated hydrocarbons. The analytes validated for the method are in the table below. The sample is collected on a coconut shell charcoal tube. After collection, the sample is desorbed in 1mL of carbon disulfide and analyzed by GC/FID (flame ionization detector).
High humidity during sampling will prevent organic vapors from being trapped efficiently on the sorbent and greatly decreases breakthrough volume.
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Hold Times, Preservatives, Preps, Collection, Analytical & Documentation | |
---|---|
Holding Time: | 30 days from sample collection to analysis for all analytes. |
Preservatives: | None specified in the method. |
Required Preps: | Coconut shell charcoal, 50/100 mg (SKC 226-01) |
Collection Method: | The method recommends a 0.01 - 0.2 L/min. flow rate and a 3 - 17L sample collection volume. |
Analytical Methodology: | GC/FID |
Documentation: | 1003 |
Analyte | Formula | CAS Number | Detection Limit | |
---|---|---|---|---|
Benzyl chloride | C7H7Cl |
100-44-7 |
0.01 |
mg |
1,4-Dichlorobenzene | C6H4Cl2 |
106-46-7 |
0.01 |
mg |
1,2-Dichloroethane | C2H4Cl2 |
107-06-2 |
0.01 |
mg |
Chlorobenzene | C6H5Cl |
108-90-7 |
0.01 |
mg |
Tetrachloroethene | C2Cl4 |
127-18-4 |
0.01 |
mg |
1,2-Dichloroethene | C2H2Cl2 |
540-59-0 |
0.01 |
mg |
Carbon tetrachloride | CCl4 |
56-23-5 |
0.01 |
mg |
Chloroform | CHCl3 |
67-66-3 |
0.01 |
mg |
Hexachloroethane | C2Cl6 |
67-72-1 |
0.01 |
mg |
1,1,1-Trichloroethane | C2H3Cl3 |
71-55-6 |
0.01 |
mg |
Bromochloromethane | CH2BrCl |
74-97-5 |
0.01 |
mg |
Bromoform | CHBr3 |
75-25-2 |
0.01 |
mg |
1,1-Dichloroethane | C2H4Cl2 |
75-34-3 |
0.01 |
mg |
1,1,2-Trichloroethane | C2H3Cl3 |
79-00-5 |
0.01 |
mg |
Trichloroethene | C2HCl3 |
79-01-6 |
0.01 |
mg |
1,2-Dichlorobenzene | C6H4Cl2 |
95-50-1 |
0.01 |
mg |
1,2,3-Trichloropropane | C3H5Cl3 |
96-18-4 |
0.01 |
mg |
* The analytes and detection limits listed for each method represent the typical detection limits and analytes reported for that particular method. Keep in mind that analyte lists may vary from laboratory to laboratory. Detection limits may also vary from lab to lab and are dependent upon the sample size, matrix, and any interferences that may be present in the sample.