Method 8021B Water

Aromatic and Halogenated Volatiles by Gas Chromatography Using Photoionization and/or Electrolytic Conductivity Detectors


This method is for the determination of aromatic and halogenated volatile organic compounds in nearly all types of aqueous matrices.  Samples can be analyzed using direct injection (preparation Method 3585 for oily matrices) or purge and trap (preparation Methods 5030, 5035), headspace (preparation Method 5021), or vacuum distillation (preparation Method 5032).  Preparation methods for ground water samples are Methods 5030, 5021 and 5032.  Analysis is performed using a gas chromatograph (GC) with a photoionization detector (PID) and an electrolyitc conductivity detector (ECD) in series.  

A single detector may be used when only the halogenated compounds (ECD) or aromatic compounds (PID) are being searched for.  The use of the dual detectors is not required but is recommended for confirmation of the compound identities. 

NOTE:  This method replaces SW-846 Methods 8021 and 8021A.


(EPA SW-846)

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Method Data

Hold Times, Preservatives, Preps, Collection, Analytical & Documentation
Holding Time:   14 days from collection to analysis
Preservatives:   Without residual chlorine: Cool to 4°C, adjust to pH < 2 with HCl. With residual chlorine: Preserve with Sodium thiosulfate solution (0.008%/L), cool to 4°C and adjust to pH < 2 with HCl.
Required Preps:   Two - 40mL VOA vials
Collection Method:   Grab sampling
Analytical Methodology:   GC/PID, GC/ECD
Documentation:   8021B

Analyte List*

Analyte Formula CAS Number Detection Limit
Ethylbenzene
C8H10
100-41-4
1
 µg/L
Styrene
C8H8
100-42-5
1
 µg/L
Benzyl chloride
C7H7Cl
100-44-7
1
 µg/L
cis-1,3-Dichloropropene
C3H4Cl2
10061-01-5
1
 µg/L
trans-1,3-Dichloropropene
C3H4Cl2
10061-02-6
1
 µg/L
n-Propylbenzene
C9H12
103-65-1
1
 µg/L
n-Butylbenzene
C10H14
104-51-8
1
 µg/L
p-Xylene
C8H10
106-42-3
1
 µg/L
4-Chlorotoluene
C7H7Cl
106-43-4
1
 µg/L
1,4-Dichlorobenzene
C6H4Cl2
106-46-7
1
 µg/L
Epichlorohydrin
C3H5ClO
106-89-8
1
 µg/L
1,2-Dibromoethane
C2H4Br2
106-93-4
1
 µg/L
Allyl chloride
C3H5Cl
107-05-1
1
 µg/L
1,2-Dichloroethane
C2H4Cl2
107-06-2
1
 µg/L
2-Chloroethanol
C2H5ClO
107-07-3
1
 µg/L
Chloromethyl Methyl Ether
C2H5ClO
107-30-2
1
 µg/L
m-Xylene
C8H10
108-38-3
1
 µg/L
bis(2-Chloroisopropyl)ether
C6H12Cl2O
108-60-1
1
 µg/L
1,3,5-Trimethylbenzene
C9H12
108-67-8
1
 µg/L
Bromobenzene
C6H5Br
108-86-1
1
 µg/L
Toluene
C7H8
108-88-3
1
 µg/L
Chlorobenzene
C6H5Cl
108-90-7
1
 µg/L
Ethyl Vinyl Ether
C4H7ClO
110-75-8
1
 µg/L
1,2,4-Trichlorobenzene
C6H3Cl3
120-82-1
1
 µg/L
Chlorodibromomethane
CHBr2Cl
124-48-1
1
 µg/L
Chloroprene
C4H5Cl
126-99-8
1
 µg/L
Tetrachloroethene
C2Cl4
127-18-4
1
 µg/L
sec-Butylbenzene
C10H14
135-98-8
1
 µg/L
1,3-Dichloropropane
C3H6Cl2
142-28-9
1
 µg/L
cis-1,2-Dichloroethene
C2H2Cl2
156-59-2
1
 µg/L
trans-1,2-Dichloroethene
C2H2Cl2
156-60-5
1
 µg/L
1,3-Dichlorobenzene
C6H4Cl2
541-73-1
1
 µg/L
Carbon tetrachloride
CCl4
56-23-5
1
 µg/L
1,1-Dichloropropene
C3H4Cl2
563-58-6
1
 µg/L
2,2-Dichloropropane
C3H6Cl2
594-20-7
1
 µg/L
Bromoacetone
C3H5BrO
598-31-2
1
 µg/L
1,1,1,2-Tetrachloroethane
C2H2Cl4
630-20-6
1
 µg/L
Chloroform
CHCl3
67-66-3
1
 µg/L
Benzene
C6H6
71-43-2
1
 µg/L
1,1,1-Trichloroethane
C2H3Cl3
71-55-6
1
 µg/L
Bromomethane
CH3Br
74-83-9
1
 µg/L
Chloromethane (Methyl chloride)
CH3Cl
74-87-3
1
 µg/L
Dibromomethane
CH2Br2
74-95-3
1
 µg/L
Bromochloromethane
CH2BrCl
74-97-5
1
 µg/L
Chloroethane
C2H5Cl
75-00-3
1
 µg/L
Vinyl chloride
C2H3Cl
75-01-4
1
 µg/L
Methylene chloride
CH2Cl2
75-09-2
1
 µg/L
Bromoform
CHBr3
75-25-2
1
 µg/L
Bromodichloromethane
CHBrCl2
75-27-4
1
 µg/L
1,1-Dichloroethane
C2H4Cl2
75-34-3
1
 µg/L
1,1-Dichloroethene
C2H2Cl2
75-35-4
1
 µg/L
Trichlorofluoromethane
CCl3F
75-69-4
1
 µg/L
Dichlorodifluoromethane
CCl2F2
75-71-8
1
 µg/L
1,2-Dichloropropane
C3H6Cl2
78-87-5
1
 µg/L
1,1,2-Trichloroethane
C2H3Cl3
79-00-5
1
 µg/L
Trichloroethene
C2HCl3
79-01-6
1
 µg/L
1,1,2,2-Tetrachloroethane
C2H2Cl4
79-34-5
1
 µg/L
1,2,3-Trichlorobenzene
C6H3Cl3
87-61-6
1
 µg/L
Hexachlorobutadiene
C4Cl6
87-68-3
1
 µg/L
Naphthalene
C10H8
91-20-3
1
 µg/L
o-Xylene
C8H10
95-47-6
1
 µg/L
2-Chlorotoluene
C7H7Cl
95-49-8
1
 µg/L
1,2-Dichlorobenzene
C6H4Cl2
95-50-1
1
 µg/L
1,2,4-Trimethylbenzene
C9H12
95-63-6
1
 µg/L
1,2-Dibromo-3-Chloropropane
C3H5Br2Cl
96-12-8
1
 µg/L
1,2,3-Trichloropropane
C3H5Cl3
96-18-4
1
 µg/L
1,3-Dichloro-2-propanol
C3H6Cl2O
96-23-1
1
 µg/L
tert-Butylbenzene
C10H14
98-06-6
1
 µg/L
Cumene (Isopropylbenzene)
C9H12
98-82-8
1
 µg/L
Cymene (4-Isopropyltoluene)
C10H14
99-87-6
1
 µg/L

* The analytes and detection limits listed for each method represent the typical detection limits and analytes reported for that particular method. Keep in mind that analyte lists may vary from laboratory to laboratory. Detection limits may also vary from lab to lab and are dependent upon the sample size, matrix, and any interferences that may be present in the sample.